catena-Poly[copper(I)-bis(μ-trifluoromethanesulfonato-κ2 O:O′)-copper(I)-bis(μ-trimethyl trithiophosphite)-κ2 P:S;κ2 S:P]
نویسندگان
چکیده
The title compound, [Cu(2)(CF(3)SO(3))(2)(C(3)H(9)PS(3))(2)](n), crystallizes as infinite chains in which two trimethyl trithio-phosphite ligands and two trifluoro-methane-sulfonate anions bridge the essentially tetra-hedrally coordinated Cu(I) ions in an alternating fashion. The P and one S atom of each trimethyl trithio-phosphite ligand are employed for coordination. The mol-ecular structure exhibits the rare motif of copper(I) bridged by two trifluoro-methane-sulfonate anions generating eight-membered rings.
منابع مشابه
catena-Poly[[copper(I)-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-2,2′-bipyridine-κ2 N:N′] bis(tetrafluoridoborate) dichloromethane 2.5-solvate]. Corrigendum
The title of the paper by Mo, Hu, Chen, Yuan & Pan [Acta Cryst. (2008), E64, m391] is corrected.[This corrects the article DOI: 10.1107/S160053680801711X.].
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The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming an eight-membered ring.
متن کاملcatena-Poly[[copper(I)-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-2,2′-bipyridine-κ2 N:N′] bis(tetrafluoridoborate) dichloromethane 2.5-solvate]
The title complex, {[Cu(2)(C(10)H(8)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)·2.5CH(2)Cl(2)}(n), contains chains of Cu(I) centres bridged alternately by two (diphenyl-phosphino)methane (dppm) and 4,4'-bipyridine (bpy) ligands. Each Cu(I) atom is coordinated by one N atom of 4,4'-bipyridine (bpy) and two P atoms of two (diphenyl-phosphino)methane (dppm) ligand, and has a trigonal-planar coordination g...
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